The Implementation of Pyrolisis of Waste Material to Bio-Oil in The KKN Course

: Kuliah Kerja Nyata (KKN) is one kind of university contribution to community. Through KKN, student also learn how to apply their knowledge and contribute it to community need. In Universitas Islam Indonesia (UII) there are two kind of KKN which are Reguler and Pembelajaran Pemberdayaan Masyarakat (PPM), which differentiate from the topic used. KKN PPM already has major topic that obtained from village destination need. The problem from KKN PPM is limitation time for student to learn about major topic before socialize to community like in KKN UII 57 unit 310-315 which has pyrolisis method as their major topic. Not all the sudent that include in unit 310-315, which come from different study, understand about pyrolisis. To settle this problem, experimental method was choose as learning method used, which help student understand about pyrolisis in limitation time. The effectiveness of this method was observed by observation, interview and questioner. The result show that expertimental method give good result. The student understand basic concept of pyrolisis process that needed in limitation time, eventhough they did not understand anything about pyrolisis method before.


INTRODUCTION
Education is important for country growth. There are many ways can be used to educate student, but there are also many factors that will affect the result. One of so many factor is learning method. Roy Killen [1] introduce two type of learning method which are Teacher Centered Learning (TCL) and Student Centered Learning (SCL). Nowadays, especially in university, SCL become more popular than TCL, because focusing student as the centered of learning will improve their ability more.
KKN is program that held by university as their contribution to community. It has so many advantage, especially for student, they can learn to socialize with community and also implement their knowledge. There are two type of KKN which are Regular and PPM. KKN PPM is type of KKN that hopefully can bridge community problem [2], and that was the reason why topic of KKN PPM should be related to village destination needed.
UII as one private college in Yogyakarta also has Regular and PPM types. The difference of both type coming from the topic used. In regular, there is no major topic, student will do program that community needed without specific purpose. In PPM, there is one major topic, so, all the program held by student should be directed to major topic as the end result (all the program will support major topic). Major topic that held in PPM should be program needed by village. In this 2018, unit 310-315 in KKN UII 57, has pyrolisis method to produce briquette and bio-oil as their major topic. Pyrolisis is thermal degradation that held at high temperature without oxygen condition (no oxidation process). The application of pyrolisis method is burning biomass (e.g. rice husk) to produce energy. In pyrolisis process, biomass will be converted to gas, liquid and char [3]. Gas that produced then converted to liquid (as bio-oil), and char that will be produced is called briquette which is one of alternative energy because it has high calorific value. Not all student in KKN learning about pyrolisis, but soon, they should educate community about pyrolisis process. So, to improve student knowledge about pyrolisis in limitation time, experimental method was International Journal of Chemistry Education Research -Vol. 2 lss. 2 August 2018 used as strategic learning method applied in KKN PPM. The result of the experimental method to deepen student knowledge about pyrolisis will be observed.

Location, time and subject experiment
Training has been hold in Chemical Laboratory. FMIPA, UII. Application will be held in village destination (Butuh Village). This experiment will be held for one month (July to August 2018). Subject experiments are all student in 310-315 unit.

Data collection
Observation, questioner, literature study

RESULT AND DISCUSSION
This experiment focused on experimental method as leaning method used because the effectiveness of the method on helping student to understand the project in limitation time. The effectiveness of the method will be shown from collected data. The data will be collected and processed to get information about effectiveness of experimental method in learning process. The question used in questioner are separated to two type which are theory question (student understanding about pyrolisis method) and instrumental question (student understanding about tools that used in pyrolisis process).
Pyrolisis method is thermal degradation of biomass to get an energy as the product, and for efficiency, usually used agricultural waste as biomass source [4]. Pyrolisis using high temperature on burning process without oxygen condition. The temperature is used from 200-500°C and produce charcoal, tar and gas (CO and also CO2) [5]. The existence of oxygen on pyrolisis process will conduct complete burning that convert all of biomass become water vapor and gas (CO2) following reaction [6]: The result from collecting and processing data are shown that majority of the student understand about basic knowledge of pyrolisis (as mentioned before) as seen at Figure 1. But, especially question about chemical reaction happen in pyrolisis process, mostly student got wrong answer. The explanation of this result is because chemical reaction is not common, people who never learn about chemical reaction, they will be confused by symbol used in reaction. Other question that has wrong answer is about pyrolisis product. Some student answers that 'ash' was pyrolisis product. This happen when doing trial eror simulation, student obtain ash when burning biomass at higher temperature. Actually ash can be produce when the burning process are upper the limit temperature of biomass to degrade thermally but, it is not expected product from pyrolisis.

FIGURE 1. Answer percentage about theoretical question
Question prepared in instrumental question type based on reactor that student used to learn (Figure 2). There are two basic part of reactor in pyrolisis which are burning furnace (symbol A) as biomass burning take place and condenser (symbol B) as part in which gas converted to liquid called bio-oil (side product of pyrolisis process).

FIGURE 2. Pyrolisis Reactor
Pyrolisis convert biomass to energy Chemical reaction when oxygen used in burning process : Pyrolisis is burning process in high temperature

Pyrolisis product
The result about instrumental question are given in Figure 3. The result shows better than theoretical question because understanding tools that student practicing with, is more easy than learning theoretical about process.

FIGURE 3. Answer Percentage about Instrumental Question
From the result of both type question, it can be concluded that experimental method, help student learning rapidly because there is majority student that do not have basic concept about pyrolisis process (84%), but after doing simulation, they can understand general knowledge about pyrolisis.

CONCLUSION
Learning method using experimental method is effective to help student understand problem in limitation time like in KKN PPM.