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Abstract

Zeolite modification with Cu has been conducted. Material modification is done by impregnating Cu through a zeolite powder reflux process with CuSO4.5H2O solution so that theoretical Cu concentration is 5% followed by oxidation and reduction of solids. Material characterization was performed by x-ray diffraction analysis (XRD), Fourier Transform Infra-Red (FTIR) and acidity testing of Cu/Zeolite catalyst.
The results showed that the crystallinity level of Cu/Zeolite did not change significantly when compared with natural zeolite. Changes occur at the intensity of the resulting peak, as at the peak of 2θ 27.826 º which is the mordenite phase in Cu-zeolite has a peak intensity of 1360, while at zeolite with peak of 2θ 27,760 º with the same phase meliki the smaller intensity of 1048. Testing the acidity of the catalyst was carried out by adsorbing pyridine into the catalyst, then calculating the adsorbed pyridine level, in the zeolite samples of pyridine adsorbed by 0.003 g / g while in the Cu-zeolite sample of 1.0574 g / g. The result of analysis with FTIR to show acidity level is seen in the range of wave number between 1450-1495 cm-1, from zeolite catalyst with wave number 1491,17 cm-1 peak intensity (% T) equal to 6,53, while at Cu-zeolite with wave number 1468.05 cm-1 peak intensity (% T) of 10.99. Testing of catalytic properties of Cu-zeolite catalyst on esterification reaction was done by taking acetic acid with concentration of 0.05 mol and methanol with concentration of 0.1 mol, then added 0.2 gram of catalyst, then reflux process for 1 hour. The results of reflux in the form of methyl esters were then analyzed by gas chromatography to see the retention time and the area of the resulting area. The use of Cu-zeolite catalysts yielding ester is indicated by the appearance of the ester peak.

Keywords

Esterifikasi Zeolit Copper

Article Details

How to Cite
Arjek, O. C. H., & Fatimah, I. (2017). Modifikasi Zeolit Dengan Tembaga (Cu) Dan Uji Sifat Katalitiknya Pada Reaksi Esterifikasi. INDONESIAN JOURNAL OF CHEMICAL RESEARCH, 3(1), 20–27. https://doi.org/10.20885/ijcr.vol2.iss1.art3

References

  1. Asnawati, D., 2014. Karakterisasi Katalis Pt-Pd/Zeolit Alam Regenerasi Pada Reaksi Hidrodenitrogenasi Piridin. Molekul 9, 36–43.
  2. do Nascimento, L.A.S., Angélica, R.S., da Costa, C.E.F., Zamian, J.R., da Rocha Filho, G.N., 2011. Comparative study between catalysts for esterification prepared from kaolins. Appl. Clay Sci. 51, 267–273. doi:10.1016/j.clay.2010.11.030
  3. Faghihian, H., Mohammadi, M.H., 2014. Acid activation effect on the catalytic performance of Al-pillared bentonite in alkylation of benzene with olefins. Appl. Clay Sci. 93–94, 1–7. doi:10.1016/j.clay.2014.02.026
  4. Fatimah, I., Rubiyanto, D., Huda, T., 2014. Effect of Sulfatation on ZirconiaPillared Montmorillonite to the Catalytic Activity in Microwave Assisted Citronellal Conversion 2014.
  5. Gupta, P., Paul, S., 2014. Solid acids: Green alternatives for acid catalysis. Catal. Today. doi:10.1016/j.cattod.2014.04.010
  6. Hart, M.P., Brown, D.R., 2004. Surface acidities and catalytic activities of acidactivated clays. J. Mol. Catal. A Chem. 212, 315–321. doi:10.1016/j.molcata.2003.11.013
  7. Kim, B.-S., Lee, S.-H., Park, Y.-T., Ham, S.-W., Chae, H.-J., Nam, I.-S., 2001. Selective catalytic reduction of NOx, by propene over copper-exchanged pillared clays. Korean J. Chem. Eng. 18, 704–710. doi:10.1007/BF02706390
  8. Suseno, A., Wijayanto, W., Khanif, M., Hastuti, R., 2003. PEMBUATAN DAN
  9. KARAKTERISASI KATALIS NIKEL PADA PADATAN PENDUKUNG
  10. ZEOLIT Ahmad. J.Kim.Sains Apl. 6, 7–10.
  11. Trisunaryanti, W., Triwahyuni, E., Sudiono, S., 2005. PREPARATION ,
  12. CHARACTERIZATIONS AND MODIFICATION OF Ni-Pd / NATURAL ZEOLITE CATALYSTS. Indones. J. Chem. 5, 48–53.
  13. Worathanakul, P., Rakpasert, N., 2016. Influence of Different Preparation
  14. Methods of Copper Loading on Na-Y Zeolite for Green Gas Emission. Int. J.
  15. Environ. Sci. Dev. 7, 885–888. doi:10.18178/ijesd.2016.7.12.899