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Submitted
July 6, 2020
Accepted
August 3, 2020
Published
August 26, 2020
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Abstract

The synthesis of diethanolamide surfactant from used cooking oil was systematically studied using modified zeolite as catalyst. The activated zeolite was obtained by dispersing natural zeolite in sulfuric acid (H2SO4) solution.  Potassium carbonate (K2CO3) was loaded into activated zeolite by wet impregnation method. The methyl ester obtained from transesterification reaction of used cooking oil was refluxed with diethanolamine (C4H11NO) solution over K2CO3/zeolite catalyst in the production of diethanolamide surfactant. The amidiation reaction over K2CO3/zeolite effectively produced 92% of diethanolamide surfactant with the highest selectivity of methyl oleate. Diethanolamide surfactant showed stable foam and emulsion with the reduction of surface tension as much as 3.3 dyne/cm.

Keywords

Zeolite Potassium carbonate Diethanolamide surfactant Used cooking oil.

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Author Biographies

Maisari Utami, Department of Chemistry, Universitas Islam Indonesia

Lecturer and researcher

Karna Wijaya, Department of Chemistry, Universitas Gadjah Mada

Lecturer and researcher

Akhmad Syoufian, Department of Chemistry, Universitas Gadjah Mada

Lecturer and researcher

Satyagraha Hakim Wicaksono, Department of Chemistry, Universitas Gadjah Mada

Student
How to Cite
Utami, M., Wijaya, K., Syoufian, A., & Wicaksono, S. H. (2020). Catalytic Synthesis of Diethanolamide Surfactant from Used Cooking Oil. EKSAKTA: Journal of Sciences and Data Analysis, 20(2), 133–138. https://doi.org/10.20885/EKSAKTA.vol1.iss2.art7
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