Main Article Content

Abstract

RecoveryCu(II) dan Pb(II) yang sebagian besar terkandung dalam limbah cair industri, baik industri besar maupun rumah tangga telah dilakukan, salah satunya adalah dengan proses adsorpsi. Penelitian ini dilakukan studi kinetika adsorpsi Cu(II) dan Pb(II) dalam limbah cair untuk mengetahui efektivitas biosorben dari ekstrak kulit buah rambutan terhadap limbah cair yang mengandung Cu(II) dan Pb(II).Penentuan kinetika adsorpsi Cu(II) dan Pb(II) dengan menggunakan biosorben dari ekstrak kulit buah rambutan dilakukan melalui beberapa model kinetika yaitu model kinetika Langmuir-Hinshelwood,Santosa, Lagergreen dan Ho. Kinetika adsorpsi Cu(II) dan Pb(II) semuanya mengikuti model kinetika Ho, yang merupakan mekanisme kinetika orde dua semu.

Keywords

kinetic adsorption biosorbent polymer

Article Details

How to Cite
Winata, W. F., & Yanti, I. (2020). Studi Kinetika Adsorpsi Cu(II) Dan Pb(II) dengan Menggunakan Biosorben dari Polimer Ekstrak Kulit Buah Rambutan. INDONESIAN JOURNAL OF CHEMICAL RESEARCH, 5(1), 1–7. https://doi.org/10.20885/ijcr.vol5.iss1.art1

References

  1. Asuquo, E.; Martin, A.; Nzerem, P.; Siperstein, F.; Fan, X., 2017, Adsorption of Cd(II) and Pb(II) ions from aqueous solutions using mesoporous activated carbon adsorbent: Equilibrium, kinetics and characterisation studies, J. Environ. Chem. Eng., vol. 5, pp.: 679–698. DOI: 10.1016/j.jece.2016.12.043
  2. Gupta, V. K.; Suhas, 2009, Application of low-cost adsorbents for dye removal—A review, J. Environ. Manag., vol. 90, pp.: 2313–2342. DOI: 10.1016/j.jenvman.2008.11.017
  3. Hayati, B.; Maleki, A.; Najafi, F.; Daraei, H.; Gharibi, F.; McKay, G., 2017, Adsorption of Pb2+, Ni2+, Cu2+, Co2+ metal ions from aqueous solution by PPI/SiO2 as new high performance adsorbent: Preparation, characterization, isotherm, kinetic, thermodynamic studies, J. Mol. Liq., vol. 237, pp.: 428–436. DOI: 10.1016/j.molliq.2017.04.117
  4. Hayati, B.; Maleki, A.; Najafi, F.; Daraei, H.; Gharibi, F.; McKay, G., 2017, Super high removal capacities of heavy metals (Pb2+ and Cu2+) using CNT dendrimer, J. Hazard. Mater., vol. 336, pp.: 146–157. DOI: 10.1016/j.jhazmat.2017.02.059
  5. He, Y.; Wu, P.; Xiao, W.; Li, G.; Yi, J.; He, Y.; Chen, C.; Ding, P.; Duan, Y., 2019, Efficient removal of Pb(II) from aqueous solution by a novel ion imprinted magnetic biosorbent: Adsorption kinetics and mechanisms, PLoS ONE, vol. 14(3), pp: e0213377. https://doi.org/10.1371/journal.pone.0213377
  6. Höhener, P.; Yu, X., 2012, Stable carbon and hydrogen isotope fractionation of dissolved organic groundwater pollutants by equilibrium sorption, J. Contam. Hydrol,, vol. 129–130, pp.: 54–61. DOI: 10.1016/j.jconhyd.2011.09.006
  7. Jr., D. L. S.; Daley, J. C.; Stephens, R. L., 2013, Lead Removal by Ion Exchange, John Wiley & Sons, Inc., Hoboken.
  8. Kavak, D., 2012, Removal of lead from aqueous solutions by precipitation statistical analysis and modeling, Desalin. Water Treat., vol. 51, pp.:1720–1726. https://doi.org/10.1080/19443994.2012.714652
  9. Li, X.; Li, H.; Xu, X.; Guo, N.; Yuan, L.; Yu, H., 2017, Preparation of a Reduced Graphene Oxide @Stainless Steel Net Electrode and Its Applicationof Electrochemical Removal Pb(II), J. Electrochem. Soc., vol. 164(4), pp.: E71–E77. DOI: 10.1149/2.1211704jes
  10. Limousin, G.; Gaudet, J.-P.; Charlet, L.; Szenknect, S.; Barthès, V.; Krimissa, M., 2007, Sorption isotherms: A review on physical bases, modeling and measurement, Appl. Geochem, vol. 22, pp.: 249–275. doi:10.1016/j.apgeochem.2006.09.010
  11. Melita, L.; Popescu, M., 2008, Removal of Cr(VI) from industrial water effluents and surface waters using activated composite membranes, Journal of Membrane Science, vol. 312(1-2), pp.: 157–162. DOI: 10.1016/j.memsci.2007.12.049
  12. Perea-Moreno, M.-A.; Sameron-Manzano, E.; Perea-Moreno, A.-J., 2019, Biomass as Renewable Energy: Worldwide Research Trends, Sustainability, vol. 11(3), 863, pp.: 1-19. https://doi.org/10.3390/su11030863
  13. Tawinteung, N.; Parkpian, P.; DeLaune, R. D.; Jugsujinda, A., 2005, Evaluation of extraction procedures for removing lead from contaminated soil, J. Environ. Sci. Health A Tox. Hazard Subst. Environ. Eng., vol. 40(2), pp.: 385–407. DOI: 10.1081/ese-200045631
  14. Tsai, W.-C.; de Luna, M. D. G.; Bermillo-Arriesgado, H. L. P.; Futalan, C. M.; Colades, J. I.; Wan, M.-W., 2016, Competitive Fixed-Bed Adsorption of Pb(II), Cu(II), and Ni(II) from Aqueous Solution Using Chitosan-Coated Bentonite, International Journal of Polymer Science, vol. 2016, pp.: 1-11. https://doi.org/10.1155/2016/1608939