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Abstract
Green shell is generally disposed of and become environmental contaminants. In this study, the green shell was used as material to adsorb dyes residue: methylene blue and methyl oranges. Green shell waste from seafood was prepared by removing the dirt then dried at room temperature. It was followed by roughly crushing before being placed in the furnace at temperatures of 300, 500, 700 and 900 °C. The selected adsorbents were sieved at 200 mesh. The adsorbents were characterized by FTIR and SEM-EDX to evaluate their functional groups and morphology. Furthermore, the adsorption process was evaluated by determining the kinetic adsorption models. The results of the FTIR characterization showed the vibration of Ca(OH)2 bone at a wave number of 3400 cm-1 and morphological analysis by SEM showed a homogeneous surface. Adsorption kinetics results obtained from the variation of time with the initial adsorbate concentration showed the kinetic model of both methylene blue and methyl orange adsorption onto the adsorbent followed a pseudo-second order.
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References
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References
J. Ma, J. Zou, B. Cui, C. yao, D. Li, Adsorption of orange II dye from aqueous solutions using phosphoric-acid modified clam shell powder, Desalination and Water Treatment 51 (2013) 6536-6544
N. Maaloul, P. Uolego, M. Rendueles, A. Ghorbal, M.Diaz, Novel bioserbents from almond shells: Characterization and adsorption properties modeling for Cu (II) ions from aqueous solutions, Journal of Environemental Chemical Engineering 5 (2017) 2944-2954
Nur Afifah A. Rahman, Mohd Ismid Mohd Said & Shamila Azman, Carbonized green mussel shell as heavy metal removal, Malaysian Journal of Civil engineering 29 Sepcial Issue 1 (2017) 56-68
M. K. Purkait, A. Maiti, S. Dasgupta, S. De, Removal of congo red using activated carbon and its regeneration, Journal of Hazardous Materials 145 92007) 287-295
Y.Y. Lau, Y.S. Wong, T.T. Teng, N. Morad, M. Rafatullah, S.A. Ong, Degradation of cationic and anionic dyes in coagulation-flocculaton process using bi-functionalized silica hybrid with aluminum-ferric as auxiliary agent, RSC Advances 5 92015) 34206-34215
Y. Zhou, L. ge, N. Fan, M.Xia, Adsorption of Congo red from aqueous solution onto shrimp shell powder, Adsorption Science & technology 36 92018) 1310-1330
A.S. Sartape, A.M. Manshare, V.V. Jadhav, P.D. Rayt, M.A. Anuse, S.S. Kolekar, Removal of malachite green dye from aqueous solution with adsorption technique using Limonia acidissima (wood apple) shell as low cost adsorbent, Arabia Journal of Chemistry 10 (2017) S3229-S3238
A. Poedjiadi, Dasar-dasar Biokimia, 2006
R. J, Martin, F.A. Ahrens, Handbook of veterinary pharmacology, in antimicrob. Drugs Hsu, W.A. Handb, Vet. Pharmacol, 2008
M. L. Granados, M.D.Z. Poves, D.M. Alonso, R. Mariscal, F.C. Galisteo, R. Moreno-Tost, J. Santamaria, J.L.G Fierro, Biodisel from sunflowwer oil by using activated calcium oxide, Applied Cataalysis B: environmental 73 (2007) 317-326
A.A. Saputra, Iriany, Adsorben Untuk Menjerap Logam, Universitas Sumetera Utara. 4 (2015) 40-45
I. Syauqiah, M. Amalia, H.A. Kartini, Analisis Variasi Waktu dan kecepatan pengaduk pada proses adsorpsi limbah logam berat dengan arang aktif, Info Teknik 12 (2011) 11-20
M. Boumediene, H. Benaissa, B. George, S. Molina, A. Merlin, Effects of pH and ionic strength on methylene blue removal from synthetic aqueous solutions by sorption onto orange peel and desrption study, Journal of Materials and Environmental Science 9 92018) 1700-1711
R. Gong, J. Ye, W. Dai, X.Yan, J. Hu, X. Hu, S. Li, H.Huang, Adsorptive removal of methyl orange and mehtylene blue from aqueous solution with figner-citron-residu-based activated carbon, Industrial and Engineering Chemistry research 52 (2013) 14297-14303
A.M, Yusof, N.A.N.N. Malek, Removal of Cr (VI) and As (V) from aqueous solutions by HDTMA-modifeis zeolite Y, Journal of Hazardous Materilas 162 (2009) 1019-1024