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Abstract
Research on utilization of snail (Pilla ampullacea) shell as CaO source for biodiesel conversion from rice bran oil has been investigated. CaO was derived by calcining the shell at pada 900oC for 2 h. The powder obtained from the process was characterized using x-ray diffraction (XRD), energy dispersive x-ray (EDX), Fourier-Transform Infra-red (FTIR) and surface basicity test. In order to test the activity of catalyst, effect of catalyst weight on the yield of conversion as studied. Results show that the derived material is composed from dominantly CaO and the material demonstrates activity in rice bran conversion into biodiesel. Compared to NaOH, the CaO catalyst exhibits more effectively active as shown by the higher yield. From varied catalyst weight, it is obtained that at the range of 2.5-10% catalyst weight does not affect significantly to the increasing yield.
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References
- Gapur, A., 2014, Pemanfaatan Cangkang Kerang Hijau, Kerang Darah, dan Remis Sebagai Katalis Heterogen Untuk Produksi Biodiesel, Penelitian, Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Riau, Pekanbaru.
- Granados, M.L., Poves, M.D.Z., Alonso, D.M., Mariscal, R., Galisteo, F.C., MorenoTost, R., SantamarÃa, J., dan Fierro, J.L.G., 2007, Biodiesel from sunflower oil by using activated calcium oxide, Applied Catalysis B: Environmental, 73, 317–326.
- Hadiyanto, H., Lestari, S.P., Widayat, W., 2016, Preparation and Characterization of Anadara Granosa Shells and CaCO3 as Heterogeneous Catalyst for Biodiesel Production, Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 21-26.
- Lesbani, A., Tamba,P., Mohadi, R., Fahmariyanti, F., 2013, Preparation Of Calcium Oxide From Achatina Fulica As Catalyst For Production Of Biodiesel From Waste Cooking Oil, Indonesian Journal of Chemistry, 13(2), 176-180.
- Mantovani, S.A, 2017, Pengaruh Jumlah Katalis dan Waktu Reaksi Terhadap Konversi Biodisel dari minyak Jelantah dengan Katalis CaO dari kulit Telur, Skripsi, Fakultas Teknik, Universitas Muhammadiyah Surakarta.
- Niju, S., Meera, K.M., Begum, S. Anantharaman, N., 2014, Modification of egg shell and its application in biodiesel production, Journal of Saudi Chemical Society, 18(5), 702-706.
- Nurhayati, Muhdarina, Linggawati, N., Anita, S., dan Amri, T.A., 2016, Preparation and Characterization of Calcium Oxide Heterogeneous Catalyst Derived from AnadaraGranosaShell for Biodiesel Synthesis, ICoSE Conference on Instrumentation, Environment and Renewable Energy, 1-8.
- Prastyo, H. S, Margaretha, Y. Y., Ayucitra, A., Ismadji, S., 2011, Transesterifikasi Minyak Kelapa Sawit dengan Menggunakan Katalis Padat dari cangkang Keong mas (Pomacea sp.), Prosiding Seminar Nasional Fundamental dan Aplikasi Teknik Kimia, Institut Teknologi Sepuluh Nopember.
- Ruhul, A. M., Kalam, M. A., Masjuki, H. H., Fattah, R. Reham, , S. S., dan Rashed, M. M., 2015, State of the art of biodiesel production processes: a review of the heterogeneous catalyst, RSC Advance, 5, 101023-101044.
- Setiowati, R., Nurhayati., Linggawati, A. 2014, Produksi Biodiesel dari Minyak Goreng Bekas Menggunakan Katalis CaO Cangkang Kerang Darah Kalsinasi 900 oC, Jurnal Online Mahasiswa, 1 (2),383-389.
- Wendi., Valentinoh ,C., Taslim., 2015. Pengaruh Suhu Reaksi dan Jumlah Katalis Pada Pembuatan Biodiesel dari Limbah Lemak Sapi dengan Menggunakan Katalis Heterogen CaO dari Kulit Telur Ayam. Jurnal Teknik Kimia USU, Vol. 4, No. 1.
References
Gapur, A., 2014, Pemanfaatan Cangkang Kerang Hijau, Kerang Darah, dan Remis Sebagai Katalis Heterogen Untuk Produksi Biodiesel, Penelitian, Fakultas Matematika dan Ilmu Pengetahuan Alam Universitas Riau, Pekanbaru.
Granados, M.L., Poves, M.D.Z., Alonso, D.M., Mariscal, R., Galisteo, F.C., MorenoTost, R., SantamarÃa, J., dan Fierro, J.L.G., 2007, Biodiesel from sunflower oil by using activated calcium oxide, Applied Catalysis B: Environmental, 73, 317–326.
Hadiyanto, H., Lestari, S.P., Widayat, W., 2016, Preparation and Characterization of Anadara Granosa Shells and CaCO3 as Heterogeneous Catalyst for Biodiesel Production, Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1): 21-26.
Lesbani, A., Tamba,P., Mohadi, R., Fahmariyanti, F., 2013, Preparation Of Calcium Oxide From Achatina Fulica As Catalyst For Production Of Biodiesel From Waste Cooking Oil, Indonesian Journal of Chemistry, 13(2), 176-180.
Mantovani, S.A, 2017, Pengaruh Jumlah Katalis dan Waktu Reaksi Terhadap Konversi Biodisel dari minyak Jelantah dengan Katalis CaO dari kulit Telur, Skripsi, Fakultas Teknik, Universitas Muhammadiyah Surakarta.
Niju, S., Meera, K.M., Begum, S. Anantharaman, N., 2014, Modification of egg shell and its application in biodiesel production, Journal of Saudi Chemical Society, 18(5), 702-706.
Nurhayati, Muhdarina, Linggawati, N., Anita, S., dan Amri, T.A., 2016, Preparation and Characterization of Calcium Oxide Heterogeneous Catalyst Derived from AnadaraGranosaShell for Biodiesel Synthesis, ICoSE Conference on Instrumentation, Environment and Renewable Energy, 1-8.
Prastyo, H. S, Margaretha, Y. Y., Ayucitra, A., Ismadji, S., 2011, Transesterifikasi Minyak Kelapa Sawit dengan Menggunakan Katalis Padat dari cangkang Keong mas (Pomacea sp.), Prosiding Seminar Nasional Fundamental dan Aplikasi Teknik Kimia, Institut Teknologi Sepuluh Nopember.
Ruhul, A. M., Kalam, M. A., Masjuki, H. H., Fattah, R. Reham, , S. S., dan Rashed, M. M., 2015, State of the art of biodiesel production processes: a review of the heterogeneous catalyst, RSC Advance, 5, 101023-101044.
Setiowati, R., Nurhayati., Linggawati, A. 2014, Produksi Biodiesel dari Minyak Goreng Bekas Menggunakan Katalis CaO Cangkang Kerang Darah Kalsinasi 900 oC, Jurnal Online Mahasiswa, 1 (2),383-389.
Wendi., Valentinoh ,C., Taslim., 2015. Pengaruh Suhu Reaksi dan Jumlah Katalis Pada Pembuatan Biodiesel dari Limbah Lemak Sapi dengan Menggunakan Katalis Heterogen CaO dari Kulit Telur Ayam. Jurnal Teknik Kimia USU, Vol. 4, No. 1.